Irradiation Effects in Polycarbonate Induced by 2.1GeV Kr Ions

TIAN Hui-Xian; JIN Yun-Fan; ZHU Zhi-Yong; LIU Chang-Long; SUN You-Mei; WANG Zhi-Guang; LIU Jie; CHEN Xiao-Xi; WANG Yan-Bin; HOU Ming-Dong

Chinese Physics C> 2002, Vol. 26> Issue(4) : 435-440

Irradiation Effects in Polycarbonate Induced by 2.1GeV Kr Ions

Institute of Modern Physics,The Chinese Academy of Science,Lanzhou 730000,China

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Polycarbonate films were irradiated with 2.1GeV Kr ions at room temperature in vacuum and in atmosphere,respectively. The ion beam induced effects were studied by means of Fourier transform infrared (FTIR) and ultraviolet visible (UV/VIS) spectroscopies in reflective mode. FTIR measurements indicate that the main effects are bond breaking,chain scissions and bond rearrangement. The creation of alkyne is the result of bond breaking and bond rearrangement. UV/VIS measurements indicate that at wavelengths of 380,450 and 500nm,the normalized absorbances follow approximately a linear relationship with the energy deposited density.

References

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TIAN Hui-Xian, JIN Yun-Fan, ZHU Zhi-Yong, LIU Chang-Long, SUN You-Mei, WANG Zhi-Guang, LIU Jie, CHEN Xiao-Xi, WANG Yan-Bin and HOU Ming-Dong. Irradiation Effects in Polycarbonate Induced by 2.1GeV Kr Ions[J]. Chinese Physics C, 2002, 26(4): 435-440.

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Received: 2001-05-08
Revised: 1900-01-01

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沈阳化工大学材料科学与工程学院沈阳 110142

Irradiation Effects in Polycarbonate Induced by 2.1GeV Kr Ions

Corresponding author: TIAN Hui-Xian,

Institute of Modern Physics,The Chinese Academy of Science,Lanzhou 730000,China

Received Date: 2001-05-08
Accepted Date: 1900-01-01
Available Online: 2002-04-05

Abstract: Polycarbonate films were irradiated with 2.1GeV Kr ions at room temperature in vacuum and in atmosphere,respectively. The ion beam induced effects were studied by means of Fourier transform infrared (FTIR) and ultraviolet visible (UV/VIS) spectroscopies in reflective mode. FTIR measurements indicate that the main effects are bond breaking,chain scissions and bond rearrangement. The creation of alkyne is the result of bond breaking and bond rearrangement. UV/VIS measurements indicate that at wavelengths of 380,450 and 500nm,the normalized absorbances follow approximately a linear relationship with the energy deposited density.